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Mechanism of Electrophilic Fluorination with Pd(IV): Fluoride Capture and Subsequent Oxidative Fluoride Transfer(, )
Electrophilic fluorinating reagents derived from fluoride are desirable for the synthesis of (18)F-labeled molecules for positron emission tomography (PET). Here, we study the mechanism by which a Pd(IV)-complex captures fluoride and subsequently transfers it to nucleophiles. The intermediate Pd(IV)...
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| Autori principali: | , , , |
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| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2013
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3870902/ https://ncbi.nlm.nih.gov/pubmed/24376910 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/C3SC52367E |
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