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Molecular-scale hydrophobic interactions between hard-sphere reference solutes are attractive and endothermic

The osmotic second virial coefficients, B(2), for atomic-sized hard spheres in water are attractive (B(2) < 0) and become more attractive with increasing temperature (ΔB(2)/ΔT < 0) in the temperature range 300 K ≤ T ≤ 360 K. Thus, these hydrophobic interactions are attractive and endothermic a...

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Autores principales: Chaudhari, Mangesh I., Holleran, Sinead A., Ashbaugh, Henry S., Pratt, Lawrence R.
Formato: Artigo
Lenguaje:Inglês
Publicado: National Academy of Sciences 2013
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Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC3870674/
https://ncbi.nlm.nih.gov/pubmed/24297918
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1312458110
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