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Molecular-scale hydrophobic interactions between hard-sphere reference solutes are attractive and endothermic
The osmotic second virial coefficients, B(2), for atomic-sized hard spheres in water are attractive (B(2) < 0) and become more attractive with increasing temperature (ΔB(2)/ΔT < 0) in the temperature range 300 K ≤ T ≤ 360 K. Thus, these hydrophobic interactions are attractive and endothermic a...
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| Main Authors: | , , , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
National Academy of Sciences
2013
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3870674/ https://ncbi.nlm.nih.gov/pubmed/24297918 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1312458110 |
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