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Reaction pathways and free energy profiles for spontaneous hydrolysis of urea and tetramethylurea: Unexpected substituent effects
It has been difficult to directly measure the spontaneous hydrolysis rate of urea and, thus, 1,1,3,3-tetramethylurea (Me(4)U) was used as a model to determine the “experimental” rate constant for urea hydrolysis. The use of Me(4)U was based on an assumption that the rate of urea hydrolysis should be...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3870011/ https://ncbi.nlm.nih.gov/pubmed/24097048 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c3ob41055b |
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