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Synthesis of Solid 2-Pyridylzinc Reagents and their Application in Negishi Reactions

[Image: see text] In search of alternatives to unstable or unreliable 2-pyridylboron reagents, we have explored two new varieties of solid, moderately air-stable 2-pyridylzinc reagents. Both reagents can be manipulated in air and are competent nucleophiles in Negishi cross-coupling reactions.

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Detalhes bibliográficos
Main Authors: Colombe, James R., Bernhardt, Sebastian, Stathakis, Christos, Buchwald, Stephen L., Knochel, Paul
Formato: Artigo
Idioma:Inglês
Publicado em: 2013
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3869385/
https://ncbi.nlm.nih.gov/pubmed/24156393
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol402798z
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