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The Pyridyldiisopropylsilyl Group: A Masked Functionality and Directing Group for Monoselective ortho-Acyloxylation and ortho-Halogenation Reactions of Arenes

A novel, easily removable and modifiable silicon-tethered pyridyldiisopropylsilyl directing group for C–H functionalizations of arenes has been developed. The installation of the pyridyldiisopropylsilyl group can efficiently be achieved via two complementary routes using easily available 2-(diisopro...

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Bibliographic Details
Main Authors: Huang, Chunhui, Chernyak, Natalia, Dudnik, Alexander S., Gevorgyan, Vladimir
Format: Artigo
Language:Inglês
Published: 2011
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC3866842/
https://ncbi.nlm.nih.gov/pubmed/24363640
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/adsc.201000975
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