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Chemical Diversification of Sialic Acid Glycosides by Stereospecific, Chemoselective Deamination
[Image: see text] Nitrosation of peracetylated NeuAc glycosides followed by treatment with sodium trifluoroethoxide and then a suitable nucleophile enables late stage modification of sialic acid glycosides with stereospecific replacement of the acetamido functionality.
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| Main Authors: | , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2013
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3865865/ https://ncbi.nlm.nih.gov/pubmed/24038615 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201303781 |
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