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A facile copper(I)-catalyzed homocoupling of terminal alkynes to 1,3-diynes with diaziridinone under mild conditions

A novel and efficient Cu(I)-catalyzed oxidative homocoupling of terminal alkynes with diaziridinone as oxidant is described. Various terminal alkynes can be transformed into the corresponding 1,3-diynes in good yields. The reaction process is base-free, operationally simple, and amenable to gram sca...

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Detalles Bibliográficos
Main Authors: Zhu, Yingguang, Shi, Yian
Formato: Artigo
Idioma:Inglês
Publicado: 2013
Assuntos:
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC3864717/
https://ncbi.nlm.nih.gov/pubmed/24089251
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c3ob41621f
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