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Alternative Synthesis of the Colorado Potato Beetle (CPB) Pheromone

A concise preparation of the pheromone secreted by the male Colorado potato beetle [viz. (3S)-1,3-dihydroxy-3,7-dimethyl-6-octen-2-one] was accomplished in 4 steps starting from 2-fluoronerol or 2-fluorogeraniol. The key step in the synthesis involves a 6-endo epoxide ring opening with ester partici...

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Detalhes bibliográficos
Main Authors: Faraldos, Juan A., Coates, Robert M., Giner, José-Luis
Formato: Artigo
Idioma:Inglês
Publicado em: 2013
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3863329/
https://ncbi.nlm.nih.gov/pubmed/24047429
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo4017056
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