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Versatile tuning of supramolecular hydrogels through metal complexation of oxidation-resistant catechol-inspired ligands
The mussel byssal cuticle employs DOPA-Fe(3+) complexation to provide strong, yet reversible crosslinking. Synthetic constructs employing this design motif based on catechol units are plagued by oxidation-driven degradation of the catechol units and the requirement for highly alkaline pH conditions...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3838863/ https://ncbi.nlm.nih.gov/pubmed/24285981 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/C3SM51824H |
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