Intermolecular crosslinking of fatty acyl chains in phospholipids: use of photoactivable carbene precursors.

Phospholipids containing photolysable carbene precursors (beta-trifluoro-alpha-diazopropionoxy and m-diazirinophenoxy groups) in omega-positions of sn-2 fatty acyl chains were prepared. Photolysis of their vesicles produced crosslinked products in 40-60% yields. Crosslinking was mostly intermolecula...

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Pubblicato in:	Proc Natl Acad Sci U S A
Autori principali:	Gupta, C M, Radhakrishnan, R, Gerber, G E, Olsen, W L, Quay, S C, Khorana, H G
Natura:	Artigo
Lingua:	Inglês
Pubblicazione:	National Academy of Sciences 1979
Soggetti:	Research Article
Accesso online:	https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC383654/ https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/288050/ https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.76.6.2595
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