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Intermolecular crosslinking of fatty acyl chains in phospholipids: use of photoactivable carbene precursors.

Phospholipids containing photolysable carbene precursors (beta-trifluoro-alpha-diazopropionoxy and m-diazirinophenoxy groups) in omega-positions of sn-2 fatty acyl chains were prepared. Photolysis of their vesicles produced crosslinked products in 40-60% yields. Crosslinking was mostly intermolecula...

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Detalhes bibliográficos
Main Authors: Gupta, C M, Radhakrishnan, R, Gerber, G E, Olsen, W L, Quay, S C, Khorana, H G
Formato: Artigo
Idioma:Inglês
Publicado em: 1979
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC383654/
https://ncbi.nlm.nih.gov/pubmed/288050
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