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Base-Induced Instability of Fluorotelomer Alcohols

The stability of fluorotelomer alcohols under basic conditions was studied. HF elimination across the CF(2)-CH(2) junction is shown to be facilitated by an intramolecular hydrogen bond, while solvation is the key determinant in the stability of alcohols of various perfluoroalkyl lengths. Finally, fl...

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Bibliographic Details
Main Authors: Tucker, William B., Mecozzi, Sandro
Format: Artigo
Language:Inglês
Published: 2013
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC3834964/
https://ncbi.nlm.nih.gov/pubmed/24273343
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.jfluchem.2013.08.010
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