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Molecular Insight into Substrate Recognition and Catalysis of Baeyer–Villiger Monooxygenase MtmOIV, the Key Frame Modifying Enzyme in the Biosynthesis of Anticancer Agent Mithramycin

Baeyer-Villiger monooxygenases (BVMOs) have been shown to play key roles for the biosynthesis of important natural products. MtmOIV, a homodimeric FAD- and NADPH-dependent BVMO, catalyzes the key frame-modifying steps of the mithramycin biosynthetic pathway, including an oxidative C-C bond cleavage,...

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Hlavní autoři: Bosserman, Mary A., Downey, Theresa, Noinaj, Nicholas, Buchanan, Susan K., Rohr, Jürgen
Médium: Artigo
Jazyk:Inglês
Vydáno: 2013
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC3830731/
https://ncbi.nlm.nih.gov/pubmed/23992662
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/cb400399b
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