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Absence of heme-localized strain in T state hemoglobin: insensitivity of heme-imidazole resonance Raman frequencies to quaternary structure.

Substitution of pentadeuterated 2-methylimidazole in (2-methylimidazole)-Fe(II)-protoporphyrin IX, a model complex for deoxyHb, shifts three bands in the low-frequency resonance Raman spectrum 380 leads to 373 cm-1, 348 leads to 345 cm-1, and 220 leads to 218 cm-1. The first of these is assigned pri...

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Bibliografiske detaljer
Udgivet i:Proc Natl Acad Sci U S A
Main Authors: Kincaid, J, Stein, P, Spiro, T G
Format: Artigo
Sprog:Inglês
Udgivet: National Academy of Sciences 1979
Fag:
Online adgang:https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC382985/
https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/284379/
https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.76.2.549
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