Paramagnetic (19)F NMR and Electrospray Ionization Mass Spectrometric Studies of Substituted Pyridine Complexes of Chromium(III): Models for Potential Use of (19)F NMR to Probe Cr(III)-Nucleotide Interaction()

The synthesis and characterization of chromium basic carboxylate complexes, [Cr(3)(O(2)CR)(6)L(3)](+), containing trifluoroacetate, 3-fluoropyridine, 3-trifluoromethylpyridine, and 4-trifluoromethylpyridine are described. The substituted pyridine ligands are used as models of DNA bases to determine...

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Main Authors: Rhodes, Nicholas R., Belmore, Ken, Cassady, Carolyn J., Vincent, John B.
Formato: Artigo
Idioma:Inglês
Publicado: 2013
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Article
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC3821766/
https://ncbi.nlm.nih.gov/pubmed/24222929
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.poly.2013.03.002
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