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Paramagnetic (19)F NMR and Electrospray Ionization Mass Spectrometric Studies of Substituted Pyridine Complexes of Chromium(III): Models for Potential Use of (19)F NMR to Probe Cr(III)-Nucleotide Interaction()
The synthesis and characterization of chromium basic carboxylate complexes, [Cr(3)(O(2)CR)(6)L(3)](+), containing trifluoroacetate, 3-fluoropyridine, 3-trifluoromethylpyridine, and 4-trifluoromethylpyridine are described. The substituted pyridine ligands are used as models of DNA bases to determine...
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Hauptverfasser: | , , , |
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Format: | Artigo |
Sprache: | Inglês |
Veröffentlicht: |
2013
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Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3821766/ https://ncbi.nlm.nih.gov/pubmed/24222929 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.poly.2013.03.002 |
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