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Theory of mass-independent fractionation of isotopes, phase space accessibility, and a role of isotopic symmetry

Key experimental and theoretical features of mass-independent fractionation (MIF) of isotopes, also known as the η-effect, are summarized, including its difference from the exit channel zero-point energy difference effect. The latter exactly cancels in the MIF. One key experimental result is that th...

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Hlavní autor: Marcus, Rudolph A.
Médium: Artigo
Jazyk:Inglês
Vydáno: National Academy of Sciences 2013
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC3816477/
https://ncbi.nlm.nih.gov/pubmed/23812747
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1213080110
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