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Carbon dioxide photolysis from 150 to 210 nm: Singlet and triplet channel dynamics, UV-spectrum, and isotope effects

We present a first principles study of the carbon dioxide (CO(2)) photodissociation process in the 150- to 210-nm wavelength range, with emphasis on photolysis below the carbon monoxide + [Image: see text] singlet channel threshold at ∼167 nm. The calculations reproduce experimental absorption cross...

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Auteurs principaux: Schmidt, Johan A., Johnson, Matthew S., Schinke, Reinhard
Format: Artigo
Langue:Inglês
Publié: National Academy of Sciences 2013
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC3816442/
https://ncbi.nlm.nih.gov/pubmed/23776249
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1213083110
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