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Synthesis of ent-Kaurane and Beyerane Diterpenoids via Controlled Fragmentations of Overbred Intermediates()

[Image: see text] In the first part of a two-phase pursuit of highly oxidized members of the ent-kaurane and beyerane diterpenoid families, steviol was identified as the ideal cyclase phase terminus. Accordingly, a synthesis of steviol has been developed. This synthesis features a polyene cyclizatio...

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Detalhes bibliográficos
Main Authors: Cherney, Emily C., Green, Jason C., Baran, Phil S.
Formato: Artigo
Idioma:Inglês
Publicado em: 2013
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3814173/
https://ncbi.nlm.nih.gov/pubmed/23861294
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201304609
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