Paramagnetic NMR Relaxation and Molecular Mechanics Studies of Chloroperoxidase-Indole Complex: Insights into the Mechanism of Chloroperoxidase-Catalyzed Regioselective Oxidation of Indole

To unravel the mechanism of CPO-catalyzed regioselective oxidation of indole, the structure of the CPO-indole complex was studied using NMR relaxation measurements and computational techniques. The dissociation constant (K(D)) of the CPO-indole complex was calculated to be approximately 21 mM. The d...

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Main Authors: Zhang, Rui, He, Qinghao, Chatfield, David, Wang, Xiaotang
Format: Artigo
Sprog:Inglês
Udgivet: 2013
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Article
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC3812394/
https://ncbi.nlm.nih.gov/pubmed/23634952
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/bi4002437
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