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Spontaneous chiral resolution directed by symmetry restriction and π-π interaction
In order to understand and rationally construct homochiral self-assembled structures from racemic molecules, two novel crystalline metal-organic frameworks with chiral cavities were developed. The homochirality of the layers in both MOFs was achieved by forming strong coordinate bonds between the C(...
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| Hauptverfasser: | , , , , , |
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| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
Nature Publishing Group
2013
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3796745/ https://ncbi.nlm.nih.gov/pubmed/24126555 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/srep02947 |
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