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The Reaction of HppE with Substrate Analogues: Evidence for Carbon-Phosphorus Bond Cleavage by a Carbocation Rearrangement

(S)-2-Hydroxypropylphosphonic acid ((S)-2-HPP) epoxidase (HppE) is an unusual mononuclear non-heme iron enzyme that catalyzes the oxidative epoxidation of (S)-2-HPP in the biosynthesis of the antibiotic fosfomycin. Recently, HppE has been shown to accept (R)-1-hydroxypropylphosphonic acid ((R)-1-HPP...

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Autors principals: Chang, Wei-chen, Mansoorabadi, Steven O., Liu, Hung-wen
Format: Artigo
Idioma:Inglês
Publicat: 2013
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC3796158/
https://ncbi.nlm.nih.gov/pubmed/23672451
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja403441x
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