Spontaneous activation of [FeFe]-hydrogenases by an inorganic [2Fe] active site mimic

Hydrogenases catalyze the formation of hydrogen. The cofactor (H-cluster) of [FeFe]-hydrogenases consists of a [4Fe-4S]-cluster bridged to a unique [2Fe]-subcluster whose biosynthesis in vivo requires hydrogenase-specific maturases. Here we show that a chemical mimic of the [2Fe]-subcluster can reco...

Disgrifiad llawn

Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Prif Awduron: Esselborn, Julian, Lambertz, Camilla, Adamska-Venkates, Agnieszka, Simmons, Trevor, Berggren, Gustav, Noth, Jens, Siebel, Judith, Hemschemeier, Anja, Artero, Vincent, Reijerse, Edward, Fontecave, Marc, Lubitz, Wolfgang, Happe, Thomas
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: 2013
Pynciau:
Article
Mynediad Ar-lein:https://ncbi.nlm.nih.gov/pmc/articles/PMC3795299/
https://ncbi.nlm.nih.gov/pubmed/23934246
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/nchembio.1311
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