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Calcium hexa­kis(dihydrogen­phosphito)­stannate(IV), Ca[Sn(H(2)PO(2))(6)], with some remarks on the so-called Ge(2)(H(2)PO(2))(6) structure type

The title compound, Ca[Sn(H(2)PO(2))(6)], was formed after a few days when tin(II) fluoride was allowed to react with phosphinic acid at ambient conditions. The structure consists of chains of Ca(2+) and Sn(4+) cations in octa­hedral sites with -3 symmetry bridged by bidentate hypophosphite anions....

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Detalhes bibliográficos
Main Authors: Gieschen, Tobias, Reuter, Hans
Formato: Artigo
Idioma:Inglês
Publicado em: International Union of Crystallography 2013
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3793664/
https://ncbi.nlm.nih.gov/pubmed/24109251
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1107/S1600536813018205
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