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Ether-Directed ortho-C–H Olefination with a Pd(II)/MPAA Catalyst
Weak coordination is powerful! A Pd(II)-catalyzed olefination of ortho-C–H bonds of arenes directed by weakly coordinating ethers is developed using mono-protected amino acid (MPAA) ligands. This finding provides a method for chemically modifying ethers, which are abundant in natural products and dr...
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| Main Authors: | , , , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2012
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3786684/ https://ncbi.nlm.nih.gov/pubmed/23239120 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201207770 |
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