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Anodic coupling of carboxylic acids to electron-rich double bonds: A surprising non-Kolbe pathway to lactones
Carboxylic acids have been electro-oxidatively coupled to electron-rich olefins to form lactones. Kolbe decarboxylation does not appear to be a significant competing pathway. Experimental results indicate that oxidation occurs at the olefin and that the reaction proceeds through a radical cation int...
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| Hauptverfasser: | , , , |
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| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
Beilstein-Institut
2013
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3778411/ https://ncbi.nlm.nih.gov/pubmed/24062822 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.9.186 |
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