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Zinc–gold cooperative catalysis for the direct alkynylation of benzofurans

The direct alkynylation of benzofurans was achieved for the first time using the hypervalent iodine reagent 1-[(triisopropylsilyl)ethynyl]-1,2-benziodoxol-3(1H)-one (TIPS-EBX) based on the cooperative effect between a gold catalyst and a zinc Lewis acid. High selectivity was observed for C2-alkynyla...

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Detalhes bibliográficos
Main Authors: Li, Yifan, Waser, Jérôme
Formato: Artigo
Idioma:Inglês
Publicado em: Beilstein-Institut 2013
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3778369/
https://ncbi.nlm.nih.gov/pubmed/24062840
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.9.204
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