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[3 + 2]-Cycloadditions of nitrile ylides after photoactivation of vinyl azides under flow conditions
The photodenitrogenation of vinyl azides to 2H-azirines by using a photoflow reactor is reported and compared with thermal formation of 2H-azirines. Photochemically, the ring of the 2H-azirines was opened to yield the nitrile ylides, which underwent a [3 + 2]-cycloaddition with 1,3-dipolarophiles. W...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Beilstein-Institut
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3778330/ https://ncbi.nlm.nih.gov/pubmed/24062837 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.9.201 |
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