Isolation and Characterization of Two Geometric Allene Oxide Isomers Synthesized from 9S-Hydroperoxylinoleic Acid by Cytochrome P450 CYP74C3: STEREOCHEMICAL ASSIGNMENT OF NATURAL FATTY ACID ALLENE OXIDES

Specialized cytochromes P450 or catalase-related hemoproteins transform fatty acid hydroperoxides to allene oxides, highly reactive epoxides leading to cyclopentenones and other products. The stereochemistry of the natural allene oxides is incompletely defined, as are the structural features require...

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Detalhes bibliográficos
Main Authors: Brash, Alan R., Boeglin, William E., Stec, Donald F., Voehler, Markus, Schneider, Claus, Cha, Jin K.
Formato: Artigo
Idioma:Inglês
Publicado em: American Society for Biochemistry and Molecular Biology 2013
Assuntos:
Lipids
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3774351/
https://ncbi.nlm.nih.gov/pubmed/23709224
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1074/jbc.M113.482521
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