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Tailoring the oxidation state of cobalt through halide functionality in sol-gel silica

The functionality or oxidation state of cobalt within a silica matrix can be tailored through the use of cationic surfactants and their halide counter ions during the sol-gel synthesis. Simply by adding surfactant we could significantly increase the amount of cobalt existing as Co(3)O(4) within the...

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Detalhes bibliográficos
Main Authors: Olguin, Gianni, Yacou, Christelle, Smart, Simon, Diniz da Costa, João C.
Formato: Artigo
Idioma:Inglês
Publicado em: Nature Publishing Group 2013
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3769890/
https://ncbi.nlm.nih.gov/pubmed/24022785
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/srep02449
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