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Studies for the enantiocontrolled preparation of substituted tetrahydropyrans: Applications for the synthesis of leucascandrolide A macrolactone
Strategies for the stereocontrolled preparations of 2,6-cis-and 2,6-trans-substituted tetrahydropyrans have been devised. These studies have explored methodology for asymmetric induction in S(E)′ reactions using chiral 1,3,2-diazaborolidine controllers. Reactions with aldehydes at −78 °C yield nonra...
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| Hauptverfasser: | , , |
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| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2011
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3763842/ https://ncbi.nlm.nih.gov/pubmed/24014149 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2011.05.020 |
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