A Simple and Efficient Synthesis of an Acid-labile Polyphosphoramidate by Organobase-catalyzed Ring-Opening Polymerization and Transformation to Polyphosphoester Ionomers by Acid Treatment

The direct synthesis of an acid-labile polyphosphoramidate by organobase-catalyzed ring-opening polymerization and an overall two-step preparation of polyphosphodiester ionomers (PPEI) by acid-assisted cleavage of the phosphoramidate bonds along the backbone of the polyphosphoramidate were developed...

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Main Authors: Zhang, Shiyi, Wang, Hai, Shen, Yuefei, Zhang, Fuwu, Seetho, Kellie, Zou, Jiong, Taylor, John-Stephen A., Dove, Andrew P., Wooley, Karen L.
Format: Artigo
Sprog:Inglês
Udgivet: 2013
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Article
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC3755629/
https://ncbi.nlm.nih.gov/pubmed/23997276
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ma400675m
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