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Gas-Phase Reactions of Cationic Vanadium-Phosphorus Oxide Clusters with C(2)H(x) (x=4, 6): A DFT-Based Analysis of Reactivity Patterns
The reactivities of the adamantane-like heteronuclear vanadium-phosphorus oxygen cluster ions [V(x)P(4−x)O(10)](.+) (x=0, 2–4) towards hydrocarbons strongly depend on the V/P ratio of the clusters. Possible mechanisms for the gas-phase reactions of these heteronuclear cations with ethene and ethane...
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| Main Authors: | , , , , , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
WILEY-VCH Verlag
2013
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3743165/ https://ncbi.nlm.nih.gov/pubmed/23322620 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201203050 |
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