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α-Bromodiazoacetamides – a new class of diazo compounds for catalyst-free, ambient temperature intramolecular C–H insertion reactions

In this work, we introduce a new class of halodiazocarbonyl compounds, α-halodiazoacetamides, which through a metal-free, ambient-temperature thermolysis perform intramolecular C–H insertions to produce α-halo-β-lactams. When carried out with α-bromodiazoacetamides bearing cyclic side chains, the th...

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Detalhes bibliográficos
Main Authors: Kaupang, Åsmund, Bonge-Hansen, Tore
Formato: Artigo
Idioma:Inglês
Publicado em: Beilstein-Institut 2013
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3740503/
https://ncbi.nlm.nih.gov/pubmed/23946835
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.9.157
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