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Studies on the Himbert Intramolecular Arene/ Allene Diels – Alder Cycloaddition. Mechanistic Studies and Expansion of Scope to All-Carbon Tethers

The unusual intramolecular arene/allene cycloaddition described thirty years ago by Himbert permits rapid access to strained polycyclic compounds that offer great potential for the synthesis of complex scaffolds. To more fully understand the mechanism of this cycloaddition reaction, and to guide eff...

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Detalhes bibliográficos
Main Authors: Schmidt, Yvonne, Lam, Jonathan K., Pham, Hung V., Houk, K. N., Vanderwal, Christopher D.
Formato: Artigo
Idioma:Inglês
Publicado em: 2013
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3727913/
https://ncbi.nlm.nih.gov/pubmed/23634642
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja4025963
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