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Interfacial Bond-Breaking Electron Transfer in Mixed Water–Ethylene Glycol Solutions: Reorganization Energy and Interplay between Different Solvent Modes

[Image: see text] We explore solvent dynamics effects in interfacial bond breaking electron transfer in terms of a multimode approach and make an attempt to interpret challenging recent experimental results (the nonmonotonous behavior of the rate constant of electroreduction of S(2)O(8)(2–) from mix...

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Autores principales: Ismailova, Oksana, Berezin, Alexander S., Probst, Michael, Nazmutdinov, Renat R.
Formato: Artigo
Lenguaje:Inglês
Publicado: American Chemical Society 2013
Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC3725609/
https://ncbi.nlm.nih.gov/pubmed/23768162
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jp405097c
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