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Expedient Synthesis of α-Substituted Fluoroethenes

A mild and efficient synthesis of 1-aryl-1-fluoroethenes from benzothiazolyl (aryl)fluoromethyl sulfones and paraformaldehyde, under DBU- or Cs(2)CO(3)-mediated conditions at room temperature, is described. A comparable diethyl fluoro(naphthalen-2-yl)methylphosphonate reagent does not react with par...

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Bibliographic Details
Main Authors: Mandal, Samir K., Ghosh, Arun K., Kumar, Rakesh, Zajc, Barbara
Format: Artigo
Language:Inglês
Published: 2012
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC3723398/
https://ncbi.nlm.nih.gov/pubmed/22349519
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c2ob07031f
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