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Deprotonation of a Borohydride: Synthesis of a Carbene-Stabilized Boryl Anion
An acidic hydride! Thanks to the presence of a π-acceptor cyclic (alkyl)(amino)carbene (CAAC) and of two electron-withdrawing nitrile groups, a borohydride reacts with a base to give a carbene-stabilized boryl anion, which reacts with carbon and metal electrophiles at the boron center. [Image: see t...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2013
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3712875/ https://ncbi.nlm.nih.gov/pubmed/23765789 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201303457 |
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