A Single Chiroptical Spectroscopic Method May Not Be Able To Establish the Absolute Configurations of Diastereomers: Dimethylesters of Hibiscus and Garcinia Acids

[Image: see text] Electronic circular dichroism (ECD), optical rotatory dispersion (ORD), and vibrational circular dichroism (VCD) spectra of hibiscus acid dimethyl ester have been measured and analyzed in combination with quantum chemical calculations of corresponding spectra. These results, along...

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Autori principali: Polavarapu, Prasad L., Donahue, Emily A., Shanmugam, Ganesh, Scalmani, Giovanni, Hawkins, Edward K., Rizzo, Carmelo, Ibnusaud, Ibrahim, Thomas, Grace, Habel, Deenamma, Sebastian, Dellamol
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2011
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Article
Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC3702036/
https://ncbi.nlm.nih.gov/pubmed/21568330
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jp202501y
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