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Anionic cascade reactions. One-pot assembly of (Z)-chloro-exo-methylenetetrahydrofurans from β-hydroxyketones

The assembly of (Z)-chloro-exo-methylenetetrahydrofurans by an original and connective anionic cascade sequence is reported. Base-catalysed condensation of β-hydroxyketones with 1,1-dichloroethylene generates, in moderate to good yields, the corresponding (Z)-chloro-exo-methylenetetrahydrofurans. Ac...

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Autors principals: Markó, István E, Schevenels, Florian T
Format: Artigo
Idioma:Inglês
Publicat: Beilstein-Institut 2013
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC3701418/
https://ncbi.nlm.nih.gov/pubmed/23843927
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.9.148
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