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Copper-catalyzed aerobic aliphatic C–H oxygenation with hydroperoxides
We report herein Cu-catalyzed aerobic oxygenation of aliphatic C–H bonds with hydroperoxides, which proceeds by 1,5-H radical shift of putative oxygen-centered radicals (O-radicals) derived from hydroperoxides followed by trapping of the resulting carbon-centered radicals with molecular oxygen.
Gorde:
| Egile Nagusiak: | , , |
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| Formatua: | Artigo |
| Hizkuntza: | Inglês |
| Argitaratua: |
Beilstein-Institut
2013
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| Gaiak: | |
| Sarrera elektronikoa: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3701382/ https://ncbi.nlm.nih.gov/pubmed/23843917 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.9.138 |
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