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Monoaryloxide Pyrrolide (MAP) Imido Alkylidene Complexes of Molybdenum and Tungsten That Contain 2,6-Bis(2,5-R(2)-pyrrolyl)phenoxide (R = i-Pr, Ph) Ligands and an Unsubstituted Metallacyclobutane on Its Way to Losing Ethylene
[Image: see text] We report the synthesis of Mo and W MAP complexes that contain O-2,6-(2,5-R(2)-pyrrolyl)(2)C(6)H(3) (2,6-dipyrrolylphenoxide or ODPP(R)) ligands in which R = i-Pr, Ph. W(NAr)(CH-t-Bu)(Pyr)(ODPP(Ph)) (4a; Ar = 2,6-disopropylphenyl, Pyr = pyrrolide) reacts readily with ethylene to yi...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
American
Chemical Society
2013
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| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3688325/ https://ncbi.nlm.nih.gov/pubmed/23794779 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om400114h |
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