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Squish and CuAAC: Additive-Free Covalent Monolayers of Discrete Molecules in Seconds

A terminal alkyne is immobilized rapidly into a full monolayer by squishing a small volume of a solution of the alkyne between an azide-modified surface and a copper plate. The monolayer is covalently attached to the surface through a copper-catalyzed alkyne-azide cycloaddition (CuAAC) reaction, and...

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Autors principals: Pellow, Matthew A., Stack, T. Daniel P., Chidsey, Christopher E.D.
Format: Artigo
Idioma:Inglês
Publicat: 2013
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC3683963/
https://ncbi.nlm.nih.gov/pubmed/23551032
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/la400172w
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