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Direct observation of ground-state lactam–lactim tautomerization using temperature-jump transient 2D IR spectroscopy

We provide a systematic characterization of the nanosecond ground-state lactam–lactim tautomerization of pyridone derivatives in aqueous solution under ambient conditions using temperature-jump transient 2D IR spectroscopy. Although electronic excited-state tautomerization has been widely studied, e...

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Hlavní autoři: Peng, Chunte Sam, Baiz, Carlos R., Tokmakoff, Andrei
Médium: Artigo
Jazyk:Inglês
Vydáno: National Academy of Sciences 2013
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC3677484/
https://ncbi.nlm.nih.gov/pubmed/23690588
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1303235110
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