New Class of Molecular Conductance Switches Based on the [1,3]-Silyl Migration from Silanes to Silenes

[Image: see text] On the basis of first-principles density functional theory calculations, we propose a new molecular photoswitch which exploits a photochemical [1,3]-silyl(germyl) shift leading from a silane to a silene (a Si=C double bonded compound). The silanes investigated herein act as the OFF...

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Библиографические подробности
Главные авторы: Löfås, Henrik, Orthaber, Andreas, Jahn, Burkhard O., Rouf, Alvi M., Grigoriev, Anton, Ott, Sascha, Ahuja, Rajeev, Ottosson, Henrik
Формат: Artigo
Язык:Inglês
Опубликовано: American Chemical Society 2013
Online-ссылка:https://ncbi.nlm.nih.gov/pmc/articles/PMC3670211/
https://ncbi.nlm.nih.gov/pubmed/23741530
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jp400062y
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