Fragmentation of Deprotonated Diacylhydrazine Derivatives in Electrospray Ionization Tandem Mass Spectrometry: Generation of Acid Anions via Intramolecular Rearrangement

The gas-phase fragmentation pathways of deprotonated diacylhydrazine derivatives (R(1)(C = O)-N(t-Bu)NH(C = O)R(2), Compounds 1–6) were investigated by the combination of electrospray ionization tandem mass spectrometry (ESI-MS/MS) and theoretical calculations. Upon collisional activation, the depro...

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Autores principales: Jiang, Kezhi, Zhang, Hu, Wang, Jianmei, Li, Fei, Qian, Mingrong
Formato: Artigo
Lenguaje:Inglês
Publicado: Public Library of Science 2013
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Research Article
Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC3660572/
https://ncbi.nlm.nih.gov/pubmed/23704891
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1371/journal.pone.0063097
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