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Dissociation or Cyclization: Options for a Triad of Radicals Released from Oxime Carbamates

[Image: see text] A set of oxime carbamates having N-alkyl and N,N-dialkyl substituents were prepared via carbonyldiimidazole intermediates. It was shown by EPR spectroscopy that they underwent clean homolysis of their N–O bonds upon UV photolysis. During photolysis of acetophenone O-allylcarbamoyl...

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Autors principals: McBurney, Roy T., Walton, John C.
Format: Artigo
Idioma:Inglês
Publicat: American Chemical Society 2013
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC3656830/
https://ncbi.nlm.nih.gov/pubmed/23600463
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja402833w
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