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Stereochemistry in self-assembled encapsulation complexes: Constellational isomerism

A previously uncharacterized form of stereochemistry, constellational isomerism, is described. The isomerism arises from different arrangements of small-molecule guests in the space of a self-assembled, cylindrical host. The cylindrical host detains three molecules each of CHCl(3), 1,2-dichloroethan...

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Detalhes bibliográficos
Main Authors: Yamanaka, Masamichi, Shivanyuk, Alexander, Rebek, Julius
Formato: Artigo
Idioma:Inglês
Publicado em: National Academy of Sciences 2004
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC365679/
https://ncbi.nlm.nih.gov/pubmed/14981269
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0308584101
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