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Design and Preparation of New Palladium Precatalysts for C-C and C-N Cross-Coupling Reactions

A series of easily prepared, phosphine-ligated palladium precatalysts based on the 2-aminobiphenyl scaffold have been prepared. The role of the precatalyst-associated labile halide (or pseudohalide) in the formation and stability of the palladacycle has been examined. It was found that replacing the...

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Autori principali: Bruno, Nicholas C., Tudge, Matthew T., Buchwald, Stephen L.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2012
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC3647481/
https://ncbi.nlm.nih.gov/pubmed/23667737
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/C2SC20903A
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