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Generation and Characterization of a Distonic Biradical Anion Formed from an Enediynone Prodrug in the Gas Phase
A negatively charged biradical intermediate was successfully generated in the gas phase via cyclization of the deprotonated bicyclo[8.3.0]trideca-12-ene-2,7-diyn-1-one precursor. The inherent negative charge of this biradical allows its characterization via collision-activated dissociation and react...
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| Main Authors: | , , , |
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| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
2013
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3638941/ https://ncbi.nlm.nih.gov/pubmed/23512422 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1007/s13361-012-0567-8 |
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