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Generation and Characterization of a Distonic Biradical Anion Formed from an Enediynone Prodrug in the Gas Phase

A negatively charged biradical intermediate was successfully generated in the gas phase via cyclization of the deprotonated bicyclo[8.3.0]trideca-12-ene-2,7-diyn-1-one precursor. The inherent negative charge of this biradical allows its characterization via collision-activated dissociation and react...

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Autori principali: Yang, Linan, Bekele, Tefsit, Lipton, Mark A., Kenttämaa, Hilkka I.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2013
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC3638941/
https://ncbi.nlm.nih.gov/pubmed/23512422
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1007/s13361-012-0567-8
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