Carbonate Templated Self-Assembly of an Alkylthiolate Bridged Cadmium Macrocycle

In the presence of Cd (ClO(4))(2) and base, a new mixed N,S-donor alkylthiolate ligand supported both carbonate formation from atmospheric CO(2) and self-assembly of a novel bis-capped puckered (CdS)(6) molecular wheel with 3-fold symmetry. The remarkable stability of the complex was demonstrated by...

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Main Authors: Lai, Wei, Berry, Steven M., Kaplan, William P., Hain, Malia S., Poutsma, John C., Butcher, Raymond J., Pike, Robert D., Bebout, Deborah C.
Format: Artigo
Sprog:Inglês
Udgivet: 2013
Fag:
Article
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC3636063/
https://ncbi.nlm.nih.gov/pubmed/23405974
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic302740j
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